Evaluation of the synergistic erosion-corrosion behaviour of HVOF thermal spray coatings

The present study examines three High Velocity Oxy Fuel deposited coatings, Tungsten Carbide, Chromium Carbide and Aluminium Oxide, under slurry erosion-corrosion conditions. Coatings produced in this manner typically exhibit superior density and hardness over alternative thermal spray technologies, therefore are suitable for use in corrosive and highly erosive environments. The scope of the study concentrates on isolation of the contributing factors of erosion, corrosion and synergy through applied electrochemistry, as well as metallographic analysis to evaluate the mechanisms causing coating degradation. The aim of which is to provide comprehensive data on the performance of the mentioned coatings under erosion-corrosion in conditions representing a flowing environment. Results demonstrate the breakdown of Chromium Carbide and Aluminium Oxide coatings result in enhanced mass loss over the uncoated S355 steel. Despite this, results have shown Tungsten Carbide with a Cobalt binder to be an effective protective coating, resulting in a significant reduction in total material loss over uncoated S355 steel

The erosion performance of particle reinforced metal matrix composite coatings produced by co-deposition cold gas dynamic spraying

This work reports on the erosion performance of three particle reinforced metal matrix composite coatings, co-deposited with an aluminium binder via cold-gas dynamic spraying. The deposition of ceramic particles is difficult to achieve with typical cold spray techniques due to the absence of particle deformation. This issue has been overcome in the present study by simultaneously spraying the reinforcing particles with a ductile metallic binder which has led to an increased level of ceramic/cermet particles deposited on the substrate with thick (>400 µm) coatings produced. The aim of this investigation was to evaluate the erosion performance of the co-deposited coatings within a slurry environment. The study also incorporated standard metallographic characterisation techniques to evaluate the distribution of reinforcing particles within the aluminium matrix. All coatings exhibited poorer erosion performance than the uncoated material, both in terms of volume loss and mass loss. The Al2O3 reinforced coating sustained the greatest amount of damage following exposure to the slurry and recorded the greatest volume loss (approx. 2.8 mm3) out of all of the examined coatings. Despite the poor erosion performance, the WC-CoCr reinforced coating demonstrated a considerable hardness increase over the as-received AA5083 (approx. 400%) and also exhibited the smallest free space length between adjacent particles. The findings of this study reveal that the removal of the AA5083 matrix by the impinging silicon carbide particles acts as the primary wear mechanism leading to the degradation of the coating. Analysis of the wear scar has demonstrated that the damage to the soft matrix alloy takes the form of ploughing and scoring which subsequently exposes carbide/oxide particles to the impinging slurry

The erosion performance of cold spray deposited metal matrix composite coatings with subsequent friction stir processing

This study forms an initial investigation into the development of SprayStir, an innovative processing technique for generating erosion resistant surface layers on a chosen substrate material. Tungsten carbide – cobalt chromium, chromium carbide – nickel chromium and aluminium oxide coatings were successfully cold spray deposited on AA5083 grade aluminium. In order to improve the deposition efficiency of the cold spray process, coatings were co-deposited with powdered AA5083 using a twin powder feed system that resulted in thick (>300 µm) composite coatings. The deposited coatings were subsequently friction stir processed to embed the particles in the substrate in order to generate a metal matrix composite (MMC) surface layer. The primary aim of this investigation was to examine the erosion performance of the SprayStirred surfaces and demonstrate the benefits of this novel process as a surface engineering technique. Volumetric analysis of the SprayStirred surfaces highlighted a drop of approx. 40% in the level of material loss when compared with the cold spray deposited coating prior to friction stir processing. Micro-hardness testing revealed that in the case of WC-CoCr reinforced coating, the hardness of the SprayStirred material exhibits an increase of approx. 540% over the unaltered substrate and 120% over the as-deposited composite coating. Microstructural examination demonstrated that the increase in the hardness of the MMC aligns with the improved dispersion of reinforcing particles throughout the aluminium matrix

Cold gas dynamic spraying of metal matrix composite coatings with subsequent friction stir processing

The present study forms an initial investigation in to the development of an innovative process to apply wear resistant surface layers to a chosen substrate material. Tungsten carbide – cobalt chromium, chromium carbide – nickel chromium and aluminium oxide coatings were cold spray deposited on to AA5083 grade aluminium and subsequently friction stir processed. In order to improve the deposition efficiency of the cold spray process, coatings were co-deposited with powdered AA5083. Friction stir processing (FSP) has been used in combination with the cold spray deposited coating to produce an engineered surface layer containing evenly dispersed reinforcing particles that reflects the constituent phases of the feedstock powder. Microstructural characterisation was performed on the test specimens making use of micro-hardness testing, light optical and scanning electron microscopy with electron dispersive spectroscopy to establish the elemental composition of the processed layer. The resulting data was contrasted with as-deposited coatings (no FSP) to highlight the variation in microstructure between the two conditions. The results demonstrate that FSP has improved the dispersal of reinforcing particles within the metal matrix composite layer with the average interparticle spacing decreasing by up to 68%. The micro-hardness of friction stir processed material shows an increase of approximately 540% over the unaltered substrate and 118% increase over the as-deposited MMC layer, in the case of the tungsten carbide reinforced coating

Performance evaluation of HVOF deposited cermet coatings under dry and slurry erosion

The present work reports on the examination of three High Velocity Oxy Fuel deposited coatings, Tungsten Carbide, Chromium Carbide and Aluminium Oxide, under slurry erosion and dry erosion conditions. The density and hardness of coatings produced in this manner are typically superior to other thermal spray processes, and are therefore suitable for use in corrosive and highly erosive environments. The primary aim of this investigation was to establish the total mass and volume loss from each coating under dry and slurry erosion testing conditions and compare the level of material loss following the respective testing regimes. The scope of the study incorporated the application of cathodic protection to prohibit the effects of corrosion in the case of slurry erosion testing. This approach ensured that any damage to the surface could be attributed to pure erosion, and as such, be assessed against the dry erosion test data. Subsequent examination of the resulting wear scars facilitated assessment of the level of damage caused by the impinging slurry. Results revealed variation in the level of degradation experienced by each coating type under the respective test conditions. Under both dry erosion and slurry erosion, Tungsten Carbide with a Cobalt binder proved an effective protective coating by exhibiting a reduction in material loss over other assessed coatings

Enhanced erosion performance of cold spray co-deposited AISI316 MMCs modified by friction stir processing

The present study reports on the erosion properties of a novel surface engineering process combining cold spray and friction stir processing. Tungsten carbide (WC-CoCr) and aluminium oxide (Al2O3) powders were cold spray co-deposited with AISI316 using a twin powder feed system. The deposited coatings were subsequently friction stir processed to refine and redistribute the reinforcing particles and remove the coating-to-substrate interface layer, thus generating a new metal matrix composite surface. Microstructural analysis of the SprayStirred (cold sprayed then friction stirred) specimens revealed significant particle refinement and improved particle distribution over the as-deposited coatings. The erosion performance of these SprayStirred surfaces was evaluated using a flowing slurry and demonstrated an 80% decrease in volume loss over the as-received AISI316 at 30° angle of attack. For SprayStirred WC-CoCr, microhardness measurements indicated an increase of approx. 530% over the unaltered AISI316 and 100% over the cold sprayed coating. These findings highlight the considerable increase in erosion performance of the SprayStirred specimens, and thus demonstrate the benefits of this innovative surface engineering process. This outcome is attributed to dispersion strengthening, imparted by the refined tungsten carbides. Furthermore, the SprayStirred WC-CoCr coating exhibited an 85% reduction in volume loss over an HVOF sprayed WC-CoCr coating

Use of non-surgical treatments on the journey to knee replacement in patients with knee osteoarthritis: a 10-year population-based case-control study

AimTo investigate temporal trends in primary care visits, physiotherapy visits, dispensed non-steroidal anti-inflammatory drugs (NSAIDs) and opioids in knee osteoarthritis (OA) patients who have and have not undergone knee replacement.MethodsWe analysed 5665 OA patients from the Skåne Healthcare Register, Sweden, who underwent knee replacement between 2015 and 2019. Controls were OA patients without knee replacement, matched 1:1 by sex, age, time and healthcare level of initial OA diagnosis, and assigned a pseudo-index date corresponding to their case's knee replacement date. Annual prevalence and prevalence ratio of primary care and physiotherapy visits, dispensed NSAIDs and opioids (all for any cause) in the 10 years before knee replacement were estimated using Poisson regression.ResultsThe annual prevalence of all-cause primary care visits, physiotherapy visits and opioid use was similar between cases and controls until 3 years before the index date when it started to increase among the cases. The year before the index date, the prevalence ratio (cases vs controls) for physiotherapy use was 1.8 (95% CI 1.7, 1.8), while for opioid use 1.6 (1.5, 1.7). NSAID use was consistently higher among cases, even 10 years before the index date when the prevalence ratio versus controls was 1.3 (1.2, 1.3), increasing to 1.8 (1.7, 1.9) in the year preceding the index date.ConclusionsManagement of OA patients who have and have not undergone knee replacement appears largely similar except for higher use of NSAIDs in knee replacement cases. Symptomatic treatments start to increase a few years before the surgery in knee replacement cases

The DINGO dataset: a comprehensive set of data for the SAMPL challenge

Part of the latest SAMPL challenge was to predict how a small fragment library of 500 commercially available compounds would bind to a protein target. In order to assess the modellers’ work, a reasonably comprehensive set of data was collected using a number of techniques. These included surface plasmon resonance, isothermal titration calorimetry, protein crystallization and protein crystallography. Using these techniques we could determine the kinetics of fragment binding, the energy of binding, how this affects the ability of the target to crystallize, and when the fragment did bind, the pose or orientation of binding. Both the final data set and all of the raw images have been made available to the community for scrutiny and further work. This overview sets out to give the parameters of the experiments done and what might be done differently for future studies

Oral abstracts 3: RA Treatment and outcomesO13. Validation of jadas in all subtypes of juvenile idiopathic arthritis in a clinical setting

Background: Juvenile Arthritis Disease Activity Score (JADAS) is a 4 variable composite disease activity (DA) score for JIA (including active 10, 27 or 71 joint count (AJC), physician global (PGA), parent/child global (PGE) and ESR). The validity of JADAS for all ILAR subtypes in the routine clinical setting is unknown. We investigated the construct validity of JADAS in the clinical setting in all subtypes of JIA through application to a prospective inception cohort of UK children presenting with new onset inflammatory arthritis. Methods: JADAS 10, 27 and 71 were determined for all children in the Childhood Arthritis Prospective Study (CAPS) with complete data available at baseline. Correlation of JADAS 10, 27 and 71 with single DA markers was determined for all subtypes. All correlations were calculated using Spearman's rank statistic. Results: 262/1238 visits had sufficient data for calculation of JADAS (1028 (83%) AJC, 744 (60%) PGA, 843 (68%) PGE and 459 (37%) ESR). Median age at disease onset was 6.0 years (IQR 2.6-10.4) and 64% were female. Correlation between JADAS 10, 27 and 71 approached 1 for all subtypes. Median JADAS 71 was 5.3 (IQR 2.2-10.1) with a significant difference between median JADAS scores between subtypes (p < 0.01). Correlation of JADAS 71 with each single marker of DA was moderate to high in the total cohort (see Table 1). Overall, correlation with AJC, PGA and PGE was moderate to high and correlation with ESR, limited JC, parental pain and CHAQ was low to moderate in the individual subtypes. Correlation coefficients in the extended oligoarticular, rheumatoid factor negative and enthesitis related subtypes were interpreted with caution in view of low numbers. Conclusions: This study adds to the body of evidence supporting the construct validity of JADAS. JADAS correlates with other measures of DA in all ILAR subtypes in the routine clinical setting. Given the high frequency of missing ESR data, it would be useful to assess the validity of JADAS without inclusion of the ESR. Disclosure statement: All authors have declared no conflicts of interest. Table 1Spearman's correlation between JADAS 71 and single markers DA by ILAR subtype ILAR Subtype Systemic onset JIA Persistent oligo JIA Extended oligo JIA Rheumatoid factor neg JIA Rheumatoid factor pos JIA Enthesitis related JIA Psoriatic JIA Undifferentiated JIA Unknown subtype Total cohort Number of children 23 111 12 57 7 9 19 7 17 262 AJC 0.54 0.67 0.53 0.75 0.53 0.34 0.59 0.81 0.37 0.59 PGA 0.63 0.69 0.25 0.73 0.14 0.05 0.50 0.83 0.56 0.64 PGE 0.51 0.68 0.83 0.61 0.41 0.69 0.71 0.9 0.48 0.61 ESR 0.28 0.31 0.35 0.4 0.6 0.85 0.43 0.7 0.5 0.53 Limited 71 JC 0.29 0.51 0.23 0.37 0.14 -0.12 0.4 0.81 0.45 0.41 Parental pain 0.23 0.62 0.03 0.57 0.41 0.69 0.7 0.79 0.42 0.53 Childhood health assessment questionnaire 0.25 0.57 -0.07 0.36 -0.47 0.84 0.37 0.8 0.66 0.4

Comment letters to the National Commission on Commission on Fraudulent Financial Reporting, 1987 (Treadway Commission) Vol. 2

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